PENGARUH PELAPISAN PERMUKAAN ELEKTRODA BALIK MENGGUNAKAN PREKURSOR SENYAWA LOGAM TERHADAP EFISIENSI DYE-SENSITIZED SOLAR CELL

    Evi Nur'Azizah, - (2024) PENGARUH PELAPISAN PERMUKAAN ELEKTRODA BALIK MENGGUNAKAN PREKURSOR SENYAWA LOGAM TERHADAP EFISIENSI DYE-SENSITIZED SOLAR CELL. S1 thesis, Universitas Pendidikan Indonesia.

    Abstract

    ABSTRAK
    Elektroda balik berbasis platina telah banyak digunakan dalam dye-sensitized solar cell (DSSC). Beberapa riset dilakukan untuk memodifikasi elektroda balik berbasis platina diantaranya dengan mengubah teknik deposisi, komposit paduan logam, modifikasi permukaan, dll. Riset ini bertujuan untuk menginvestigasi pengaruh perlakuan permukaan elektroda balik platina menggunakan larutan prekursor nickel (II) chloride (NiCl2), copper (II) chloride (CuCl2), dan copper (I) thiocyanate (CuSCN) dengan teknik sederhana yaitu spin-coating. Elektroda balik platina dibuat menggunakan teknik screen-printing kemudian dilakukan proses deposisi larutan prekursor dan dipanaskan pada suhu 105°C. Efisiensi Pt/CuSCN dan Pt/CuCl2 meningkat menjadi 5.25% dan 5.14%, dibandingkan dengan kontrol Pt (4.58%). Meskipun Pt/CuSCN memiliki konduktivitas yang rendah dari hasil karakterisasi electrochemical impedance spectroscopy (EIS). Nilai JSC nya mencapai 12.73 mA/cm², lebih tinggi dibandingkan dengan Pt (11.9 mA/cm²). Sementara itu, efisiensi Pt/NiCl2 turun menjadi 4.47% dikarenakan rendahnya VOC and JSC. Sebagai hasil dari riset ini, perlakuan permukaan pada elektroda balik platina menggunakan CuSCN dan CuCl2 memiliki keterlibatan dalam peningkatan performa DSSC.

    Kata kunci: dye-sensitized solar cell, counter electrode, surface modification

    ABSTRACT
    The platinum-based counter electrode (Pt-CE) has been widely used in dye-sensitized solar cells (DSSC). Several research of modifying platinum-counter electrodes such as altering the deposition techniques, composite metal alloy, surface modification, etc. This research aims to investigate the effect of surface treatment on platinum-based counter electrodes using a solution precursor of nickel (II) chloride (NiCl2), copper (II) chloride (CuCl2), and copper (I) thiocyanate (CuSCN) with a simple technique of spin-coating. Platinum-based counter electrode was prepared using a screen-printing technique and afterward, the deposition of solution precursors then heated at 105°C. Pt/CuSCN and Pt/CuCl2 increased efficiency of 5.25% and 5.14% respectively, compared with the control Pt (4.58%). Even Pt/CuSCN is less conductive by electrochemical impedance spectroscopy characterization. The JSC reaches 12.73 mA/cm², higher than Pt (11.9 mA/cm²). Meanwhile, the efficiency of Pt/NiCl2 decreases to 4.47% due to the lower VOC and JSC. As a result, this Pt-CE surface treatment using CuSCN and CuCl2 has implications to raise the DSSC’s performance.

    Keywords: dye-sensitized solar cell, counter electrode, surface modification

    Baca Full Text klik disini
    [thumbnail of S_FIS_2003933_Title.pdf] Text
    S_FIS_2003933_Title.pdf
    Download (403kB)
    [thumbnail of S_FIS_2003933_Chapter1.pdf] Text
    S_FIS_2003933_Chapter1.pdf
    Download (183kB)
    [thumbnail of S_FIS_2003933_Chapter2.pdf] Text
    S_FIS_2003933_Chapter2.pdf
    Restricted to Staf Perpustakaan
    Download (371kB) | Request a copy
    [thumbnail of S_FIS_2003933_Chapter3.pdf] Text
    S_FIS_2003933_Chapter3.pdf
    Download (697kB)
    [thumbnail of S_FIS_2003933_Chapter4.pdf] Text
    S_FIS_2003933_Chapter4.pdf
    Restricted to Staf Perpustakaan
    Download (460kB) | Request a copy
    [thumbnail of S_FIS_2003933_Chapter5.pdf] Text
    S_FIS_2003933_Chapter5.pdf
    Download (105kB)
    [thumbnail of S_FIS_2003933_Appendix.pdf] Text
    S_FIS_2003933_Appendix.pdf
    Restricted to Staf Perpustakaan
    Download (1MB) | Request a copy
    Official URL: https://repository.upi.edu/
    Item Type: Thesis (S1)
    Additional Information: https://scholar.google.com/citations?view_op=list_works&hl=id&user=BqsYNg0AAAAJ ID SINTA Doesn Pembimbing: ANDHY SETIAWAN : 6040311
    Uncontrolled Keywords: dye-sensitized solar cell, elektroda balik, modifikasi permukaan dye-sensitized solar cell, counter electrode, surface modification
    Subjects: Q Science > Q Science (General)
    Q Science > QC Physics
    Divisions: Fakultas Pendidikan Matematika dan Ilmu Pengetahuan Alam > Program Studi Fisika - S1 > Program Studi Fisika (non kependidikan)
    Depositing User: EVI NUR'AZIZAH
    Date Deposited: 12 Sep 2024 09:35
    Last Modified: 12 Sep 2024 09:35
    URI: http://repository.upi.edu/id/eprint/124117

    Actions (login required)

    View Item View Item