Rahman, Taufik (2015) SINTESIS DAN KARAKTERISASI KARBON BERPORI DARI JERAMI PADI DENGAN MENGGUNAKAN METODE EKSTRAKSI ALKALI. S1 thesis, Universitas Pendidikan Indonesia.
Abstract
Penelitian ini bertujuan untuk melakukan sintesis partikel karbon berpori dari jerami padi sebagai sumber karbon menggunakan metode ekstraksi alkali sederhana. Proses ekstraksi dilakukan pada suhu 60°C selama 2 jam diiringi pengadukan 600 rpm. Pada penelitian ini dilakukan variasi KOH dengan rasio massa KOH:abu:aquades sebesar 0:1:8; 0,50:1:8; 1,50:1:8; dan 4,50:1:8; sedangkan variasi aquades dilakukan dengan rasio massa KOH:abu:aquades sebesar 1,50:1:8 dan 1,50:1:16. Evaluasi keberhasilan proses sintesis karbon berpori dilakukan dengan beberapa karakterisasi, diantaranya: X-Ray Diffraction (XRD), Thermo Gravity Differential Thermal Analysis (TG-DTA), Atomic Absorption Spectroscopy (AAS), Fourier Transform Infra Red (FTIR), dan Transmission Electron Microscopy (TEM). Hasil TG-DTA menunjukkan bahwa jerami padi terkonversi menjadi 22,27% abu dengan pemanasan 513,25°C. Hasil gravimetri menunjukkan bahwa abu jerami padi mengandung 84,60% silika. Hasil AAS menunjukkan bahwa abu jerami padi mengandung logam oksida, seperti: K2O (6,39%), CaO (0,88%), MgO (0,44%), dan Fe2O3 (0,16%). Hasil XRD menunjukkan tidak adanya puncak pada difraktogram yang mengindikasikan bahwa produk adalah partikel karbon amorf. Hasil FTIR menunjukkan puncak pada 1382 dan 1656 cm-1, mengindikasikan C-H bending dan C=O stretching dari karbon. Selain itu, silika juga terdapat pada produk karbon yang diindikasikan oleh puncak pada 460; 771; dan 840 cm-1 yang merepresentasikan Si-O-Si bending, O-Si-O symmetric stretching, dan Si-O-Si stretching. Hasil TEM menunjukkan bahwa produk berbentuk bulat dengan diameter rata-rata 161,99 nm dan ukuran pori rata-rata 8,50 nm. The aim of this research was to synthesize porous carbon particles from rice straw as carbon sources using a simple alkaline extraction method. The extraction process was conducted at temperature of 60°C with continous stirring at 600 rpm for 2 hours. In this experiment, using varied KOH with mass ratio of KOH:ash:aquades at 0:1:8; 0.50:1:8; 1.50:1:8; and 4.50:1:8; while varied aquades with mass ratio of KOH:ash:aquades at 1.50:1:8 and 1.50:1:16. Evaluation of reliability of the process to get porous particles, several analyses were conducted: an X-Ray Diffraction (XRD), a Thermo Gravity Differential Thermal Analysis (TG-DTA), an Atomic Absorption Spectroscopy (AAS), a Fourier Transform Infra Red (FTIR), and a Transmission Electron Microscopy (TEM). The TG-DTA results showed that rice straw converted to 22.27% ash by heating at 513.25°C. The gravimetric results showed that rice straw ash containing 84.60% of silica. The AAS results showed that rice straw ash containing metal oxide, such as K2O (6.39%), CaO (0.88%), MgO (0.44%), and Fe2O3 (0.16%). The XRD results showed no peak at diffractogram indicating that product is amorphous carbon. FTIR results showed peaks at 1382 and 1656 cm-1, indicating C-H bending and C=O stretching from carbon. In addition, the silica was consited in carbon product indicated by peaks at 460; 771; and 840 cm-1 which representing Si-O-Si bending, O-Si-O symmetric stretching, and Si-O-Si stretching, respectively. The TEM results showed that the product was spherical particles with an average diameter of 161.99 nm and an average pores size of 8.50 nm.
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| Item Type: | Thesis (S1) |
|---|---|
| Additional Information: | No. Panggil : S KIM RAH s-2015; Pembimbing : I. Eng. Asep Bayu Deni Nandiyanto, II. Rer. Nat. Ahmad Mudzakir |
| Uncontrolled Keywords: | karbon berpori, jerami padi, ekstraksi alkali, silika |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Fakultas Pendidikan Matematika dan Ilmu Pengetahuan Alam > Program Studi Kimia - S1 > Program Studi Pendidikan Kimia |
| Depositing User: | Users 25223 not found. |
| Date Deposited: | 05 Jan 2016 02:11 |
| Last Modified: | 05 Jan 2016 02:11 |
| URI: | http://repository.upi.edu/id/eprint/18925 |
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