Maulana Ibrohim, - (2023) ANALISIS PENGARUH LAPISAN rGO PADA LaFeO3 YANG DI-DOPING Gd SEBAGAI MATERIAL SENSOR GAS ETANOL MENGGUNAKAN DENSITY FUNCTIONAL THEORY. S1 thesis, Universitas Pendidikan Indonesia.
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Abstract
LaFeO3 (LFO) banyak digunakan sebagai material penyusun sensor gas dengan mekanisme adsorpsi oksigen. Namun, material LFO dalam aplikasi sensor gas etanol belum memiliki sensitivitas, selektivitas, dan temperatur kerja yang optimum. Doping Gadolinium (Gd) banyak digunakan dalam aplikasi sensor gas untuk meningkatkan sensitivitas sensor gas. Selain itu, material reduce graphene oxide (rGO) banyak digunakan dalam aplikasi sensor gas untuk meningkatkan selektivitas dan temperatur kerja sensor gas. Pada penelitian ini dianalisis pengaruh doping Gd dan penambahan lapisan rGO pada material LFO terhadap sensitivitas dan selektivitas berdasarkan energi adsorpsi sistem dengan molekul gas etanol menggunakan Density Functional Theory (DFT). Berdasarkan penelitian ini, diperoleh bahwa adanya doping Gd dan lapisan single layer rGO dapat meningkatkan energi adsorpsi. Penambahan lapisan rGO menunjukkan memberikan eskalasi energi adsorpsi sekitar 9.45%, dari -2.49 eV pada LFO yang di-doping Gd menjadi -2.75 eV ketika diberi lapisan rGO. Hal tersebut menunjukkan potensi material LFO yang di-doping Gd dan diberi lapisan rGO sebagai material sensor gas etanol. Kata kunci: LaFeO3, Gadolinium, reduce graphene oxide, density functional theory, sensor gas, gas etanol LaFeO3 (LFO) is commonly used as a material for gas sensor applications. However, the LFO material in ethanol gas sensor applications can still improve sensitivity, selectivity, and working temperature parameters. Gadolinium (Gd) doping is widely used in gas sensor applications to increase the sensitivity of gas sensors. In addition, reduced graphene oxide (rGO) materials are commonly used in gas sensor applications to increase gas sensors' selectivity and working temperature. In this study, the effect of Gd doping and the addition of an rGO layer on LFO material was analysed on sensitivity and selectivity based on the adsorption energy of the system with ethanol gas molecules. Density Functional Theory studies were conducted to yield insight into the LGFO or LGFO @ rGO – ethanol gas interactions also the sensitivity and selectivity improvement by adsorption energy. Based on this research, it was found that the presence of Gd doping and single layer rGO could increase the adsorption energy value. The addition of the rGO layer showed an escalation of the adsorption energy value of about 9.45%, – 2.49 eV in the LGFO to – 2.75 eV LGFO @ rGO. This result shows the potential of LGFO and LGFO @ rGO as potential ethanol gas sensor materials. Keywords: LaFeO3, Gadolinium, reduce graphene oxide, density functional theory, gas sensor, ethanol
| Item Type: | Thesis (S1) |
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| Additional Information: | Link Google Scholar: https://scholar.google.co.id/citations?user=sjVM1rkAAAAJ&hl=en ID SINTA Dosen Pembimbing: Endi Suhendi: 5976806 Waslaluddin: 6099556 |
| Uncontrolled Keywords: | LaFeO3, Gadolinium, reduce graphene oxide, density functional theory, sensor gas, gas etanol LaFeO3, Gadolinium, reduce graphene oxide, density functional theory, gas sensor, ethanol |
| Subjects: | L Education > L Education (General) Q Science > QC Physics |
| Divisions: | Fakultas Pendidikan Matematika dan Ilmu Pengetahuan Alam > Jurusan Pendidikan Fisika > Program Studi Fisika (non kependidikan) |
| Depositing User: | Maulana Ibrohim |
| Date Deposited: | 16 Feb 2023 06:32 |
| Last Modified: | 16 Feb 2023 06:32 |
| URI: | http://repository.upi.edu/id/eprint/88342 |
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